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COMPOSITE SOLID PROPELLANT

Ammonium Perchlorate Composite Propellant (APCP)

NH₄ClO₄ + Al + HTPB (composite)
Combined Fuel/OxidizerExcellent — 10-25 year storage life when properly encasedLow in solid form; combustion produces HCl gas
NH₄ClO₄ + Al + HTPB (composite)
FORMULA
CHEMICAL
240–270 s
SECONDS
ISP RANGE
1.75–1.82 g/cm³
KG/M³
DENSITY
N/A (combustion temp ~3,300°C)
°C
BOILING POINT
N/A (composite mixture)
G/MOL
MOLECULAR WEIGHT
Low in solid form; combustion produces HCl gas
RATING
TOXICITY

Ammonium Perchlorate Composite Propellant (APCP) (NH₄ClO₄ + Al + HTPB (composite)) is a composite solid propellant propellant used as a combined fuel/oxidizer. Excellent — 10-25 year storage life when properly encased. Typical ISP: 240–270 s seconds.

APCP is the dominant solid rocket propellant formulation, consisting of ammonium perchlorate oxidizer crystals (65-72%) bound in an HTPB matrix with aluminum powder fuel (16-20%). It powers the solid rocket boosters on the Space Shuttle, Ariane 5, and most modern solid rocket motors. The propellant is cast as a thick slurry and cured into a rubber-like solid grain.

FormulaNH₄ClO₄ + Al + HTPB (composite)
🔬TypeComposite Solid Propellant
🔥RoleCombined Fuel/Oxidizer
Density1.75–1.82 g/cm³ kg/m³
Molecular WeightN/A (composite mixture) g/mol
🌡Boiling PointN/A (combustion temp ~3,300°C)°C
Melting PointN/A (decomposes at ~200°C)°C
🎨Color / AppearanceGray to off-white
📦StorabilityExcellent — 10-25 year storage life when properly encased
CryogenicNo

Developed in the 1950s-60s at JPL and Aerojet. Became the standard solid propellant formulation for launch vehicle boosters and strategic missiles.

High thrust, simple design (no pumps), reliable, long storage life, high density impulse

Cannot be shut down, limited Isp, HCl exhaust pollution, difficult to manufacture large grains

🚀ISP Range240–270 s seconds
ToxicityLow in solid form; combustion produces HCl gas
CryogenicNo
Self-contained (fuel + oxidizer in one grain)
Shuttle SRBs
SLS SRBs
Ariane 5 EAP
GEM-63XL
Vega P80/Z23/Z9

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